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All Jarrell
Ash monochromators and spectrographs use a diffraction grating as
the dispersive element. Choosing a grating for a monochromator or
spectrograph should be a function of the overall performance expected
and the spectral region to be studied. Here is a brief description
of gratings and what factors to consider when selecting a grating.
A grating a
system of close, straight, equidistant, and parallel lines or bars
positioned on a polished surface to produce spectra by diffraction.
Classically ruled gratings are produced mechanically by burnishing
groove after groove into a layer of aluminum which has been deposited
evenly on a quartz substrate with a diamond tool. Gratings can also
be produced by using laser beams to produced interference fringes.
Such gratings are called holographic gratings.
Gratings are
characterized by a blaze wavelength and a groove density. The blaze
wavelength is the wavelength at which the grating is at its maximum
efficiency. Groove density is the number of grooves per mm on the
grating surface. The useful range of a grating can be conveniently
described by the 2/3 - 3/2 rule which simply gives the range of
a grating to be lower limit = 2/3 Blaze; upper limit = 3/2 Blaze.
Thus, for a grating with a blaze of 400 nm, its useful range is
266 to 600 nm. It is not unusual to be able to operate the grating
with reasonable efficiency above the "magic'' 3/2 value. However,
this is not suggested on the short wavelength side below the "magic''
2/3 value.
a.
Wavelength in microns (mm)
b.
Wavelength in microns (mm)
Figure 1. Efficiency curve for gratings a.) 600 grooves/mm,
1 mm blaze and b.) 1200 grooves/mm, 500 nm blaze.
Gratings range in density from 2400 to 30 grooves/mm. Gratings with
denser groove spacing (i.e. 2400 and 1200 g/mm) are normally used
in the UV-VIS range providing high resolution and low dispersion.
Coarser gratings (i.e. 50 and 30 g/mm) are normally used in the
IR region providing low resolution and high dispersion.
Grating performance
is affected by aberrations created in the ruling process and by
the optical design of the instruments in which the gratings are
used. The most common aberration is due to periodic imperfections
in the groove spacing of the grating. These imperfections arise
from the mechanical ruling process, and are commonly called "ghosts.''
Current ruling processes reduce "ghosts'' to a minimum in all
but the most critical experiments.
The holographic
process produces gratings virtually free of spacing errors, thus
no "ghosts". Until recently holographic gratings had very
poor efficiencies-especially when compared to classically ruled
gratings. However, modern holographic gratings have been produced
with efficiencies very near those of classically ruled gratings.
A holographic grating may be better suited for applications requiring
low stray light and or dense groove spacing. Ruled gratings are
normally chosen when efficiency and overall throughput of the optical
system are of primary concern. They are ideal for use in the IR
spectrum.
Thermo Vision
Colorado offers two types of gratings: "Certified Precision,''
and "Quality Controlled.'' Certified Precision gratings are
high quality gratings in which the irregularity in the 1st order
is better than 0.125 waves. Quality controlled gratings are typically
one wave irregular. Thermo Vision Colorado offers the gratings listed
in the table below.
Sizes Available:
Minimum 10 x 10 mm (width x length); maximum 110 x 110 mm (width
x length), thickness 3, 5, 10, 16 or 22 mm. Other odd sizes are
also available. Please ask!